1_2.3 HYDROGEOCHEMICAL PATTERNS OF THE AQUIFER IN HOLOCENE AND UPPER NEOPLEISTOCENE ALLUVIAL DEPOSITS OF THE KALUSH–HOLYNSKY POTASH SALT DEPOSIT

UDC 556.12:546.45:504

Malkova Y., Panasyuk M., Sosonna N.

 

Malkova Y. Ph.D. (Geol. Sciences), jun. res. fellow, State Institution “Institute of Environmental Geochemistry of the National Academy of Sciences of Ukraine”, ave. Academician Palladin, 34a, Kyiv, 03680, Ukraine E-mail: malkovayanakiev@gmail.com, ORCID: https://orcid.org./0000-0002-6215-9901

Panasyuk M. Ph.D. (Ingen. Sciences), sen. res. fellow, Institute for Safety Problems of Nuclear Power Plants National Academy of Sciences of Ukraine, Kirova str 36a, Chornobyl, 07270, Ukraine E-mail: nipanasyuk53@gmail.com ORCID: https://orcid.org/0000-0003-3607-344X

Sosonna N. jun. res. fellow, Institute for Safety Problems of Nuclear Power Plants National Academy of Sciences of Ukraine, Kirova str 36a, Chornobyl, 07270, Ukraine E-mail: natalyasosonnaya@gmail.com ORCID:Orcid.org/0000-0002-9913-3457

 

DOI:

Pages:

PDF

 

HYDROGEOCHEMICAL PATTERNS OF THE AQUIFER IN HOLOCENE AND UPPER NEOPLEISTOCENE ALLUVIAL DEPOSITS OF THE KALUSH–HOLYNSKY POTASH SALT DEPOSIT

 

Abstract. The main potential sources of salinization of the aquifer within the Holocene and Upper Neopleistocene alluvial deposits of the Kalush–Holynsky potash salt deposit have been analyzed. The hydrogeological conditions of the aquifer, which serves as the only source of drinking water for the Kalush region, have been studied. To determine the levels and directions of salinization spread, as well as to forecast changes in hydrogeological and hydrogeochemical conditions, water samples were collected from 16 observation wells located within the drainage influence zone of the Dombrovsky quarry, and groundwater levels were measured. Based on the sampling results and analyzed chemical data from 2019–2023, the dynamics of mineralization changes and the sources of contamination of the gravel–pebble aquifer were determined. The hydrogeological conditions of the aquifer in holocene and upper neopleistocene alluvial deposits — the only source of drinking water in the Kalush region — have been studied. To determine the levels and directions of salinization spread, as well as to forecast changes in hydrogeological and hydrogeochemical conditions, water samples were collected from 16 observation wells located within the drainage influence zone of the Dombrovskyi quarry, and groundwater levels were measured. Based on the sampling results and chemical analyses for 2019–2023, the dynamics of mineralization changes and the sources of contamination in the aquifer in holocene and upper neopleistocene alluvial deposits  were determined. A mineralization map of the study area was constructed. A salinization halo is identified downstream from the area of tailings ponds No. 1, 2, and 3, and the shaft zone. Groundwater mineralization values are 59 900 mg/dm³ (No. 9), 24 400 mg/dm³ (No. 11), and 3 519 mg/dm³ (No. 10), respectively. A powerful source of groundwater contamination is tailing dumps No. 1 and No. 4. The influence of these dumps on aquifer salinization is observed in wells No. 16 and, likely, No. 65, with mineralization values of 17 849 mg/dm³ and 29 211 mg/dm³, respectively. Overall, it was found that elevated mineralization values are observed in a group of wells located within the direct impact zone of surface technogenic reservoirs.

 

Keywords: Kalush–Holynsky potash salt deposit, aquifer in Holocene and Upper Neopleistocene alluvial deposits, saline contamination.

 

References

  1. Dovgy iS.O., KorzhnevM.N., TrofymchukO.M., KuryloM.M., YakovlievYe.O., MyrontsovM.L., AS., VirshyloI.V., KosharnaS.K., SukhinaE.N., MalkovaYa.O. (2022). Institute of telecommunications and global information space of NAS of Ukraine. Kyiv: Nika-Center, 200 p. (in Ukrainian).
  2. Ivano-Frankivsk National Technical University of Oil and Gas (2023). Report under contract No. 4M, topic 11/2023. Ivano-Frankivsk: Ivano-Frankivsk National Technical University of Oil and Gas. 130 p.
  3. Kosharna S, Malkova Y. (2021), Conference Proceedings, 15th International Conference Monitoring of Geological Processes and Ecological Condition of the Environment, Nov 2021, Volume 2021, p.1 – 5. DOI: https://doi.org/10.3997/2214-4609.20215K2031.
  4. Kuzmenko, E. D., Bagriy, S. M. (2013). Ecological-geological monitoring of the Kalush mining region-plans and realities. Paper presented at the GeoInformatics 2013 – 12th International Conference on Geoinformatics: Theoretical and Applied Aspects, Geoinformatics 2013.
  5. Malkova Y. O., Kovalenko I. O., Dolin V. V., Demikhov Y. M., Panasiuk M. I., Sosonna N. V., BagriyS.M, KuzmenkoE. D., OnyshchenkoI. P., Saravana KumarU., BuzynnyiM. G. (2023). Journal of Environmental Radioactivity, Elsevier, 257, p. 107083. https://doi.org/10.1016/i.ienvrad.2022.107083
  6. Malkova Y., Kopylenko O., Panasiuk M., Sosonna N., Bagriy S., Onyshchenko I. (2022). 16th International conference monitoring of geological processes and ecological condition of the environment, Nov 2022, Volume 2022, p.1 – 5. DOI: https://doi.org/10.3997/2214-4609.2022580186
  7. Malkova Ya., Kovalenko I., Dolin V., Panasyuk M., Demikhov Yu., Sosonna N., Bagriy S., Kuzmenko E.. (2022). Geochemistry of technogenesis, 7 (35), 73–77. (in Ukrainian). DOI https://doi.org/10.32782/geotech2022.35.14
  8. Noosphere Group LLC (2020). Report on topic 1/2020. Ivano-Frankivsk: Noosphere Group LLC. 29 p.
  9. Noosphere Group LLC (2021). Report on topic 1/2021. Ivano-Frankivsk: Noosphere Group LLC. 160 p.
  10. Noosphere Group LLC (2019). Report on topic 1/2019. Ivano-Frankivsk: Noosphere Group LLC. 31 p.
  11. , PanasiukM., MalkovaYa., KovalenkoI., BagriyS., BuzynnyiM. (2023). 17th International conference Monitoring of geological processes and ecological condition of the environment. Nov 2023, Volume 2023, p.1 – 5. DOI: https://doi.org/10.3997/2214-4609.2023520185

State Research Institute of Halurgy (N.D.I. “Halurgy”) (2005). Conducting comprehensive geological studies aimed at determining (forecasting) changes in the natural state of the geological environment in potash mining areas to prevent their negative impact on human activity